Abstract
THE controversy over the solid-liquid-vapour (S–L–V) triple point of carbon began in 1849 (ref. 1). Since then, investigators have developed widely differing points of view which are discussed here. Some believe the triple-point pressure is ∼105 Pa (∼1 atm), whereas others believe it is ∼107 Pa (∼100 atm). Over the past 40 yr, the 107 Pa view has dominated but the evidence is not entirely convincing. In the past few years, new evidence has been obtained that apparently ends the controversy at least from the standpoint of the proper order of magnitude of the pressure.
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References
Channey, N. K., Hamister, V. C. & Glass, S. W. Trans. Am. electrochem. Soc. 67, 107–150 (1935).
Bundy, F. P. J. chem. Phys. 38, 618–630 (1963).
Stull, D. R. & Prophet, H. Nat, Stand. Ref. Data Ser. (NBS, Washington D. C., 1971).
Dolton, T. A., Goldstein, H. E. & Maurer, R. E. in AIAA Prog. Astronaut. Aeronaut. Thermal Design Principles of Spacecraft and Entry Bodies (ed. Bevans, J. T.) 21, 179–201 (Academic, New York, 1969).
Covington, M. A., Liu, G. N. & Lincoln, K. A. AIAA J. 15, 1174–1179 (1977).
Lundell, J. H. & Dickey, R. R. in AIAA Prog. Astronaut. Aeronaut Thermophysics of Spacecraft and Outer Planet Entry Probes (ed. Smith, A. M.) 56, 405–422 (Academic, New York, 1977).
Maurer, R. E., Powers, C. A., Hartman, G. J. & Foster, T. F. Vaporization of Graphitic Materials at High Mass Transfer Rates, Air Force Materials Laboratory ( AFML-TR-76-41, 1976).
Whittaker, A. G., Kintner, P. L., Nelson, L. S. & Richardson, N. Paper No. TP-3, Abstr. 12th Biennial Conf. on Carbon, 45–47 (The American Carbon Society, 1975).
Whittaker, A. G. & Kintner, P. L. High-Temperature Sci. 9, 71–72 (1977).
Whittaker, A. G. Science 200, 763–764 (1978).
Whittaker, A. G., Page No. MG-4(1), Abstr. 13th Biennial Conf. on Carbon 413 (The American Carbon Scoiety, 1977).
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WHITTAKER, A. The controversial carbon solid–liquid–vapour triple point. Nature 276, 695–696 (1978). https://doi.org/10.1038/276695a0
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DOI: https://doi.org/10.1038/276695a0
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