Properties of Fluids
Properties of Fluids
INTRODUCTION
NATURE OF ENGINEERING MECHANICS
𝐹 = 𝑀𝑎
a. Standard Acceleration of Gravity ( g ):
SI: g = 9.80655 m/s2 ≈ 9.81 m/s2 English: g = 32.174 ft/s2≈ 32.2 ft/s2
b. Mass (M) and Weight (W): W = Mg
c. Conversion Factors:
1 lb = 4.448 N = 444,800 Dy
1 slug = 32.174 lbm = 14.5939 kg 1 N = 1 x 105 Dy = 100,000 Dy
Example 1: What is the weight of a kilogram mass at the earth’s surface where the
acceleration is 9.81 m/s2?
Solution: By the law of universal gravitation
𝑊 = 𝑀𝑔
𝑚
𝑊 = 1𝑘𝑔 9.81 2
𝑠
𝑘𝑔 ∙ 𝑚
𝑊 = 9.81 𝑜𝑟 9.81𝑁
𝑠2
Example 2: What is the weight of a pound mass at the earth’s surface where the
acceleration is 32.174 ft/s2?
Solution:
First find the mass in slugs:
1 𝑠𝑙𝑢𝑔 1
1 𝑙𝑏𝑚 𝑥 = 32.174 𝑠𝑙𝑢𝑔
32.174𝑙𝑏𝑚
Then
1 𝑓𝑡
𝑊 = 𝑀𝑔 = 𝑠𝑙𝑢𝑔 𝑥 32.174 2
32.174 𝑠
𝑊 = 1 𝑙𝑏𝑓
Example 3: How many pounds a kilogram mass at the earth’s surface where the
acceleration is 9.80655 m/s2?
Solution:
𝑊 = 𝑀𝑔
𝑚
𝑊 = 1 𝑘𝑔 9.80655 = 9.80655 𝑁
𝑠2
1 𝑙𝑏
𝑊 = 9.80655 𝑁 𝑥 = 2.205 𝑙𝑏
4.448 𝑁
d. Common Prefixes of SI Units:
CLASSIFICATION OF FLUIDS
a. Compressibility:
- incompressible
- compressible
b. Viscosity:
- Non-viscous
- Viscous
- Newtonian
- Non-Newtonian
c. Ideal Fluid:
DEFINITION OF A FLUID
GAS
1. Molecules are very far apart.
2. Very compressible.
3. Expand indefinitely when external pressure is removed.
4. Can be held in equilibrium only when it is completely enclosed.
5. No free surface
LIQUID
1. Molecules are little closer.
2. Relatively incompressible.
3. Cohesion between molecules holds them together except of its
own vapor and does not expand indefinitely.
4. Can be held in equilibrium both in an open and close space.
5. May have a free surface (i.e a surface from which all pressure is
removed, except that of its own vapor) .
PHYSICAL PROPERTIES OF FLUIDS
Note: The basic relation between the weight and the mass of a
body is
𝑊
𝑀= 𝑜𝑟 𝑊 = 𝑀𝑔
𝑔
where g = 9.81 m/s2, the acceleration of gravity at sea level.
The weight of the body varies directly as the amount of g which, at sea level,
from the equator to the poles, has a variation of only one-half percent. On the
other hand, the weight decreases with an increase in elevation from sea level
and this change is approximately one-thirtieth percent for each kilometer
increase in elevation.
3. Specific weight, y: the force exerted by gravity on a unit volume of fluid, or
𝐖
𝛄=
𝐕
Units: 𝑙𝑏
English System: 𝑓𝑡 3
𝑑𝑦
Metric System: 𝑐𝑚3
S.I. : 𝑁
𝑚3
Note: This relationship is true for liquids where varies slightly
regardless of temperature and pressure. For gases, is computed from Charles
and Boyles laws which give
English:
𝑝
𝛾= 𝐰𝐡𝐞𝐫𝐞 p - absolute pressure
𝑅𝑇 1545 𝑙𝑏∙𝑓𝑡
R- gas constant ( )
𝑀 𝑙𝑏𝑚 ∙°𝑅
𝑁−𝑚 8312 𝑁 ∙ 𝑚
𝑅= ( )
𝑘𝑔 − °𝐾 𝑀 𝑘𝑔 ∙ °𝐾
1.986 𝐵𝑇𝑈
( )
𝑀 𝑙𝑏 ∙ °𝑅
M – molecular weight
T=°K, °K =273 + °C
Alternative unit of R: J/kg-K; Btu/lb-°R; ft-lbf/lb-°R
4. Specific Volume, 𝜈:
1
The reciprocal of the density, or 𝜈 =
𝜌
𝑓𝑡 3 𝑐𝑚3 𝑚3
English: 𝑀𝑒𝑡𝑟𝑖𝑐: 𝑔𝑟 𝑆. 𝐼: 𝑘𝑔
𝑠𝑙𝑢𝑔𝑠
5. Mass Density, 𝜌(𝑟ℎ𝑜):
The mass per unit volume of the fluid, or
𝑀 𝑊 𝛾
𝜌= = =
𝑉 𝑔𝑉 𝑔
𝑠𝑙𝑢𝑔𝑠
Units: English, 𝑓𝑡 3
𝑔𝑟
Metric, 𝑐𝑚3
𝑘𝑔
S.I., 𝑚3
𝑘𝑔 𝑔 𝑔
𝑙𝑏 𝑁 𝜌𝑤 = 1000 = 1.0 = 1.0
𝛾𝑤 = 62.4 3 or 9810 3 ; 𝑚3 𝑐𝑚3 𝑚𝑙
𝑓𝑡 𝑚
7. Dynamic (Absolute) Viscosity, μ (mu): the property of a fluid which determines the
amount of its resistance to a shearing stress.
Note: The shearing stress, τ (Tau), and the viscosity, μ (Mu) are related by,
𝑑𝑣 𝑙𝑏 𝑁 𝑑𝑣
𝜏=𝜇 , , , is the velocity gradient
𝑑𝑥 𝑓𝑡 2 𝑚𝑚2 𝑑𝑥
Units of μ :
𝑙𝑏 − sec 𝑁−𝑠 𝑘𝑔
English System: SI =
𝑓𝑡 2 𝑚2 𝑚−𝑠
𝑑𝑦𝑛𝑒 − 𝑠 𝑁−𝑠 Dynamic viscosity of water at
𝑀𝑒𝑡𝑟𝑖𝑐: 𝑝𝑜𝑖𝑠𝑒(𝑃) = = 0.1
𝑐𝑚2 𝑚2 20 ˚ C, μ = 1 cP = 0.01P
=1 mN-s/m2
X
There is shear between the fluid
element because of indifference of
velocities, τ
Body of fluid
Direction of flow
b b’ F
Assumptions/Observations:
a. Closely spaced plates, y is very small.
b. Lower plate is fixed.
c. Force F exerted on upper plate with area A imparting a velocity u to the plate.
d. No slip at the boundaries, velocity of fluid same as boundary.
e. Line ab moves to the line ab’ after time interval.
f. Velocity distribution is linear.
g. Based on experimental observations: The applied force is proportional to the
area and velocity gradient. μ is the constant of proportionality.
𝐴𝑢 𝑢
𝐹=𝜇 𝑜𝑟 𝜏 = 𝜇
𝑦 𝑦 𝑑𝑢
h. Differential form ( Newton’s Law of Viscosity): 𝜏 = 𝜇
𝑑𝑦
PHYSICAL PROPERTIES TABLE OF WATER IN SI UNITS
Dynamic
Density Gas constant, R
Gas Viscosity
(kg/m3) (N-m/kg-°K)
(Pa-s)
Air 1.205 1.80 x 10-5 287
𝑘𝑁 𝑥1000𝑁
𝛾𝑤 9.81 3 9.81 3 𝑘𝑔
𝜌𝑤 = 𝑚 = 𝑚
𝑔 = 9.81 𝑚 𝑚
9.81 2
= 1000 3
𝑚
𝑠 2 𝑠
𝑁 − 𝑠2
Note : 1 = 1𝑘𝑔
𝑚
𝑘𝑁 𝑘𝑁
𝛾𝑚𝑒𝑟𝑐𝑢𝑟𝑦 = 𝑠𝑚𝑒𝑟𝑐𝑢𝑟𝑦 𝛾𝑤𝑎𝑡𝑒𝑟 = 13.55 9.81 = 133
𝑚3 𝑚3
𝑘𝑔 𝑘𝑔
𝜌𝑚𝑒𝑟𝑐𝑢𝑟𝑦 = 𝑠𝑚𝑒𝑟𝑐𝑢𝑡𝑦 𝜌𝑤𝑎𝑡𝑒𝑟 = 13.55 1000 3 = 13,550 3
𝑚 𝑚
b) A gallon of water weighs 4.08 lb. Compute the following:
1) Mass in slugs
2) Mass in kg
3) Volume in cu. ft.
Solution.
𝑊 4.08𝑙𝑏 𝑙𝑏 − 𝑠 2
1) Mass in slugs: 𝑀 = → 𝑀=
𝑓𝑡 = 0.1267
𝑓𝑡
(𝑠𝑙𝑢𝑔𝑠)
𝑔 32.2 2
𝑠
4.448𝑁
4.08𝑙𝑏 ⋅ 𝑁 − 𝑠2
𝑙𝑏
2) Mass in kg: 𝑀= 𝑚 = 1.85
𝑚
(𝑘𝑔)
9.81 2
𝑠
𝑘𝑔 𝑘𝑔
𝑜𝑟 = 1.26 1000 3 = 1260 3
𝑚 𝑚
The specific weight is,
𝛾𝑔𝑙𝑦𝑐𝑒𝑟𝑖𝑛 = 𝜌𝑔𝑙𝑦𝑐𝑒𝑟𝑖𝑛 ⋅ 𝑔
𝑘𝑔 𝑚
= 1260 ⋅ 9.81
𝑚3 𝑠2
𝑁 𝑘𝑁
= 12,360 3 𝑜𝑟 12.360 3
𝑚 𝑚
6. Kinematic Viscosity, v (nu): the ratio of the dynamic viscosity to its
mass density, or
𝜇
𝜈=
𝜌
Units of ν :
𝑓𝑡 2 𝑚2
English System: S.I. :
sec sec
𝑐𝑚2
Metric System: 𝑠𝑡𝑜𝑘𝑒 =
sec
7. Adhesion: Attractive forces between molecules of different types. This
enables a liquid to stick to another body.
8. Cohesion: Attractive forces between molecules of the same type. The
property of a liquid that resists tensile stress.
9. Surface Tension, 𝜎 (sigma): the effect of cohesion between particles
of the liquid at its surface.
𝑁
Unit: English System: 𝑙𝑏 SI :
𝑓𝑡 𝑚
10. Capillarity: is the tendency of liquid to be raised or depressed in a
a narrow tube, or capillary tube which is due to relative strength
of cohesive and adhesive forces. If adhesion has a greater effect
than cohesion, the liquid will rise at the point where it comes in
contact with another body. If cohesion is prevalent, the liquid will
depressed. The capillary rise or depression is defined by.
2𝜎 cos 𝜃 2𝜎 cos 𝜃
ℎ= =
𝛾𝑟 𝜌𝑔𝑟
where θ
σ σ
σ = surface tension in units of
force per unit length
θ = wetting angle h
r
γ = specific weight of liquid
r = radius of tube
h = capillary rise
ρ = density of liquid
g = gravitational acceleration
DERIVATION OF CAPILLARY RISE
𝑇 = 𝑉γ
σ N/m σcosθ N/m
θ σ N/m σcos 𝜃(2π𝑟) = 𝜋𝑟 2 ℎ(γ)
σsinθ N/m
W=Vγ 2σ cos 𝜃
h=
W (weingt of the γ𝑟
cylindrical h
body of fluid)
2σ cos 𝜃
h=
ρ𝑔𝑟
11. Vapor Pressure, 𝑝𝑣 : the pressure exerted by the vapor as
evaporation of the liquid takes place within a closed space.
𝑙𝑏 − 𝑠
= 2.088𝑥10−5
𝑓𝑡 2
b) The Kinematic viscosity in the English system
𝜇 𝜇𝑔 𝑙𝑏
𝜈= = 𝑤ℎ𝑒𝑟𝑒 𝛾 = 62.32 3 (𝑤𝑎𝑡𝑒𝑟) 𝑎𝑡 68°𝐹
𝜌 𝛾 𝑓𝑡
2.088𝑥10−5 32.2 𝑓𝑡 2
𝜈= = 1.079𝑥10−5
62.32 sec
Example 2. The kinematic viscosity unit of 1 ft2/sec is equivalent to how
many stokes?
Solution:
𝑓𝑡 2 2.54𝑐𝑚 12𝑖𝑛 2 𝑐𝑚2
𝜈= 1 ⋅ = 929 𝑜𝑟 929𝑠𝑡𝑜𝑘𝑒𝑠
sec 𝑖𝑛 𝑓𝑡 sec
𝑓𝑡
where: 𝑅 = 53.3 𝑎𝑖𝑟
°𝑅
15°𝐶 = 59°𝐹
𝑙𝑏 144𝑖𝑛2
14.7 2 𝑙𝑏
𝑖𝑛 𝑓𝑡 2 = 0.0765 3
𝛾= 𝑓𝑡
𝑓𝑡
53.3 460 + 59°𝐹
°𝑅
−4
𝑓𝑡 2
= 1.58𝑥10
sec
Example 5. At a depth of 8 km in the ocean the pressure is 81.8 MPa.
Assume specific weight at the surface is 10.05 kN/cu.m and that the
𝑁
average volume modulus is 2.34𝑥109 2 for the pressure
𝑚
range.
(a) What will be the change in specific volume between that at the
surface and at that depth?
(b) What will be the specific volume at that depth?
(c ) What will be the specific weight at that depth?
Diagram
𝒌𝑵
γ1 = 10.05 𝒎𝟑 p1 = 0 Ocean surface
1 𝑵
= 10.05 x 𝟏𝟎𝟑 𝒎𝟑
𝑁
𝐸𝑣 = 2.34𝑥109
𝑚2 8 km
2
p2 = 81.8 MPa
= 81.8 x 106 N/m2
Determine Solution:
(a) Change in specific volume, Δv (a) For Δv
𝑚 𝑁
𝑁 9.81 81.8𝑥106
𝐸𝑣 = 2.34𝑥109 2 8 km
Δ𝑣 = − ⋅ 𝑠2 𝑚 2
𝑚 𝑁 𝑁
10.05𝑥103 3 2.34𝑥109 2
𝑚 𝑚
2 𝑚 3
p2 = 81.8 MPa
= 81.8 x 106 N/m2 Δ𝑣 = −3.412𝑥10−5
𝑘𝑔
( b ) For Specific volume at 8 km depth, v2,
𝑚 3
Δ𝑣 = 𝑣2 − 𝑣1 = −3.412𝑥10−5
𝑘𝑔
3
1 𝑚
𝑣2 − = −3.412𝑥10−5
𝜌1 𝑘𝑔
3
𝑔 𝑚
𝑣2 − = −3.412𝑥10−5
𝛾1 𝑘𝑔
𝑚
9.81 𝑚 3
𝑣2 = 𝑠2− 3.1412𝑥10−5
𝑁 𝑘𝑔
10.05𝑥103 3
𝑚
𝑚 3
𝑣2 = 9.420𝑥10−4
𝑘𝑔
(c) For specific weight at 8 km depth, γ2
𝛾2 = 𝜌2 ⋅ 𝑔
1
𝛾2 = ⋅ 𝑔
𝑣2
1 𝑚
𝛾2 = 3 ⋅ 9.81 𝑠 2
𝑚
9.420𝑥10−4
𝑘𝑔
𝑁
= 10,414 3
𝑚
Example 6. The radius of the tube as shown in the figure is 1 mm.
The surface tension of water at 20 ˚C is equal to 0.0728 N/m . For a
water –glass θ = 0˚, determine (a) capillary rise in the tube in mm,
(b) total force due surface tension, and (c) weight of water that will
rise in the tube.
θ
σ
2r
Solution.
( a) Capillary rise in the tube in mm
2𝜎 cos 𝜃 2 0.0728 cos 0 °
ℎ= = = 0.0148𝑚. = 14.8𝑚𝑚
𝜌𝑔𝑟 1000 9.81 0.001
( b ) Total force due to surface tension =F
=σ
𝐹 = (𝜎 cos 𝜃)(𝜋𝑑) =σ
( c ) Weight of water
𝑁
𝑊 = 𝛾𝑉= 9810 𝜋 0.001𝑚 2 0.0148𝑚
𝑚3
= 4.57𝑥10−4 𝑁
Example 7. Calculate the density, specific weight and specific volume of
chlorine gas at 25 °C and under a pressure of 600 kPa absolute. The gas
constant R for chlorine is 117 N – m/ kg - °K.
Solution:
𝑝 600𝑥103 𝑘𝑔
𝜌= = = 17.209 3
𝑅𝑇 117 25 + 273 𝑚
𝑉 = 1.201 − 213.468𝑥 2
1.2 m/s 𝑑𝑉
= −426.936𝑥
𝑑𝑥
Note: The negative sign denotes that V is decreasing as x increases.
x (m)
15 cm 3.75 cm = 0.0375 m
𝜏
𝑁
𝜏 = 4.755
𝑚2
PROPERTY CHANGES IN IDEAL GAS
For any ideal gas experiencing any process or changes, the equation
of state is given by:
𝑝1 𝑉1 𝑝2 𝑉2 (Universal Gas Law) (1)
=
𝑇1 𝑇2
When temperature is held constant, equation 1 reduces to
𝑝 𝑉 =𝑝 𝑉 (Boyle’s Law) (2)
1 1 2 2
𝑝𝑉 = 𝑛 𝑅𝑢 𝑇
𝑤ℎ𝑒𝑟𝑒:
𝑝 = 𝑎𝑏𝑠𝑜𝑙𝑢𝑡𝑒 𝑝𝑟𝑒𝑠𝑠𝑢𝑟𝑒
𝑉 = 𝑣𝑜𝑙𝑢𝑚𝑒
𝑛 = 𝑛𝑢𝑚𝑏𝑒𝑟 𝑜𝑓 𝑚𝑜𝑙𝑒𝑠
𝑇 = 𝑎𝑏𝑠𝑜𝑙𝑢𝑡𝑒 𝑡𝑒𝑚𝑝𝑒𝑟𝑎𝑡𝑢𝑟𝑒
𝐽
𝑉𝑎𝑙𝑢𝑒 𝑎𝑛𝑑 𝑆𝐼 𝑢𝑛𝑖𝑡𝑠 𝑜𝑓 𝑅𝑢 ∶ 8.312
𝑚𝑜𝑙 ∙ °𝐾
Perfect – gas law (derived from eq. 1)
pvs = RT (a)
Certain simplifications result from writing the perfect-gas law on a mole basis.
Then
𝑝𝑣ഥ𝑠 =MRT ( d)
where 𝑣𝑠 - volume per mole ( m3/mole, ft3/mole)
pV= nMRT ( e)
n – number of moles
Note nM = m Note equations ( c) and (e).
Rearranging ( e) pV= nMRT
𝑝𝑉 (f)
= 𝑀𝑅
𝑛𝑇
MR – is called universal gas constant
Solution:
8312 𝑁 ∙ 𝑚
From eq. (g) 𝑅=
𝑀 𝑘𝑔 − °𝐾
8312 𝑁∙𝑚 𝑁∙𝑚
𝑅= =188.91
44 𝑘𝑔−°𝐾 𝑘𝑔−°𝐾
𝑝
Then from eq. (b) ρ=
𝑅𝑇
0.90 𝑥 106 𝑁/𝑚2
ρ=
𝑁∙𝑚
188.91 0 (273 + 20)0 𝐾
𝑘𝑔 ∙ 𝐾
𝑘𝑔
ρ = 16.26 3
𝑚
SPECIFIC WEIGHT AND DENSITY OF AIR
Temperature Viscosity μ
°C Pa – s x 105
0 1.71
10 1.76
20 1.81
30 1.86
40 1.90
60 2.00
80 2.09
100 2.18
Holman’s equation for finding μ of air is
1. If a certain gasoline weighs 7 kN/m3, what are the values of its density,
specific volume, and specific gravity relative to water at 15 °C?
2. A cubic meter of air at 101.3 kPa and 15 °C weighs 12 N. What is its
specific volume?
3. The density of alcohol is 790 kg/m3. Calculate its specific weight, specific
weight, specific gravity and specific volume.
4. A certain gas weighs 16 N/m3 at a certain temperature and pressure.
What are the values of its density, specific volume, and specific gravity
relative to air weighing 12 N/m3?
5. Compute the number of watts which are equivalent to one horsepower.
( 1 HP = 550 ft-lb/sec; W = 107 dynes-cm/sec; 1 lb = 444,800 dynes).
6. A city of 6000 population has an average total consumption per person
per day of 100 gallons. Compute the daily total consumption of the city in
cubic meter per second ( 1 ft3 = 7.48 gallons ).
7. What are the density, specific weight, specific gravity, dynamic viscosity,
and kinematic viscosity of carbon dioxide at a pressure of 250
kN/m2 absolute and a temperature of 20 ⁰C?
8. Mercury does not adhere to a glass surface, so when a glass tube is
immersed in a pool of mercury, the meniscus is depressed, as shown in the
figure. The surface tension of mercury is 0.514 N/m and the angle of contact is
40 ⁰C. Find the depression distance in a 1 –mm glass tube,
9. The vapor pressure of water at 100 ⁰C is 101 kN/m2, because water boils under
these conditions. The vapor pressure of water decreases approximately linearly
with decreasing temperature at a rate of 3.1 kN/m2 ⁰C. Calculate the boiling
temperature of water at an altitude of 3000 m, where the atmospheric pressure is
69 kN/m2 absolute.
SPECIAL PROBLEM: What is the pressure within 1 mm spherical droplet of
water relative to the atmospheric pressure outside? The surface tension for a
water-air surface is 0.073 N/m.
𝑇 = 𝜎𝜋𝐷
𝑁
𝜎,
𝑚
𝜋 2
𝐹 =𝑝∙ 𝐷
4
𝐷
Total force on the surface of water, F =Total surface tension, T
𝜋 2
𝑝∙ 𝐷 = 𝜎𝜋𝐷 𝑁
4 4 0.073 𝑚 𝑁
4𝜎 𝑝= = 292 2
𝑝= 0.001 𝑚 𝑚
𝐷