NFS tends to be living in the kernel, which sounds like a terrible place for TLS. That said, IPSec lives in the kernel to some extent, you could layer NFS on top of ipsec....
Netflix's TLS support is an extremely limited hack that suits their performance needs. It does not support initial session negotiation or rekeying. They do the former in userspace before handing off a symmetric key to the kernel, and drop connections in the latter case, relying on the client to reconnect. There's no chance it will be merged to FreeBSD; it's not a general solution.
As long as we're talking about TLS and IPSec, though, I'd point to Wireguard as maybe something viable for kernel use.