That's a bit like saying "Just got a monitor. What's good to look at on it?" ;-)
The world of VR is so diverse it's tricky to recommend things without knowing you.
Personally I'm not much of a gamer so I tend to be interested in narrative stuff, abstract visuasation and geometry stuff or just exploring interesting environments.
And the games I do like tend to have one or more of the above qualities.
You might be an RPG fan, a strategy gamer, an art aficionado , looking for productivity or educational tools or any number of things.