The difference is that Redis is single-threaded, the value proposition of Redis was/is a fast (in-memory) simple (single-threaded) server to serve things so much faster than a traditional DB. It was a perfect fit and became popular with the Ruby/Rails community,etc since those environments combined with traditional SQL servers are slogs compared to what a fast server like Redis could do.
As good as Redis is, modern computers with multiple cores potentially leaves a lot of performance on the table. Garnet seems to be a well designed multithread KV-store (though sadly the benchmark page doesn't list benchmark for more complex objects even if the simple cases looks good).
I feel like most of the obsession over Redis came from old school cgi-esque server side apps that couldn't easily maintain state themselves...
Nowadays your webapp is often a persistent, multi-threaded web server where you can cache whatever temporary state you want far more efficiently than reaching out to a KV store.
Using postgres and caching common results becomes a non-issue even at scale. The main area where a super fast KV store shines is when you need to share a very large number of keys, where many servers only need to access a random subset and isn't interested in maintaining the full set and getting updates on a bus, where the values often change and needs to be revalidated so caching is ineffective, and where persistence is not needed so a database doesn't matter and a lighter KV store is acceptable.