The same could be said for someone who says "I read books all the time." You could look at it as someone being unproductive (hey if you're reading a book, you're probably not working!) or you could look at it as someone educating themselves.
The headers and footers are optional. In my Linux Firefox, if I go to the File menu, select the Print option, go to the "Options" tab, there's a whole "Header and Footer" section where you can set them to whatever you want, including "--blank--".
Details of this print dialog might, of course, depend on your GNOME version, your distribution, and the time of month, like everything on Linux.
Now the quality of the text is a separate issue; I haven't actually done any printing from a web browser on Linux in a few years, so I have no idea what that looks like nowadays.
The main problem I have is links. The printing to PDF doesn't care about <a> links. It will linkify anything that looks like a URL or an email address, but that means that I have to have JS put the url in, plus it's ugly to have the urls there at all.
As far as links go, I already treat the resume like a print document; all the URLs are written out explicitly, have their own lines where appropriate. (I guess that's why I haven't run into the problem yet.)
It doesn't look very nice when printed/PDFed by printing to PDF.